Biodegradability of Surfactants 1995 Edition Contributor(s): Karsa, D. R. (Editor), Porter, M. R. (Editor) |
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ISBN: 0751402060 ISBN-13: 9780751402063 Publisher: Springer OUR PRICE: $208.99 Product Type: Hardcover - Other Formats Published: December 1994 Annotation: The widespread use of surfactants and their release into the environment has resulted in an upsurge of interest in the biodegradability of these compounds. This volume, written by a team of industrial and academic authors, provides an overview of the science and technology of the subject. |
Additional Information |
BISAC Categories: - Gardening - Technology & Engineering | Textiles & Polymers - Science | Chemistry - Physical & Theoretical |
Dewey: 541 |
LCCN: 94078346 |
Physical Information: 0.85" H x 6.94" W x 9.1" (1.18 lbs) 257 pages |
Descriptions, Reviews, Etc. |
Publisher Description: The awareness and development of 'biodegradable' surfactants pre-dates current pressures by the environmental movement by nearly three decades, wherein a responsible industry mutually agreed to replace 'hard', non-biodegradable com- ponents of household detergents by 'soft', biodegradable alternatives, without course to legislation. The only requirement at that time was for surfactants used in detergents to exhibit a 'primary biodegradability' in excess of 80%; this referring to the disap- pearance or removal from solution of the intact surface active material as de- tected by specified analytical techniques. This proved useful, as observed environmental impacts of surfactants, e.g. visible foam on rivers, are associated with the intact molecule. Test methods for 'primary biodegradability' were eventually enshrined in EU legislation for nonionic surfactants (Directive 821242/EEC, amended 73/404IEEC) and for anionic surfactants (Directive 8212431EEC, amended 73/405IEEC). No approved test methods and resultant legislation have been developed for cationic and amphoteric surfactants to date. The environmental classification of chemical substances, which of course includes surfactants, and associated risk assessment utilises a second criterion - 'ready biodegradability'. This may be assessed by a number of methods which monitor oxygen uptake (BOD), carbon dioxide production or removal of dis- solved organic carbon (DOC). Some surfactants which comply with the above Detergents Directive are borderline when it comes to 'ready biodegradability'. |