| Volume 25: Optical Methods of Investigating Solid Bodies 1965 Edition Contributor(s): Skobel Tsyn, D. V. (Editor) |
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ISBN: 1468472089 ISBN-13: 9781468472080 Publisher: Springer OUR PRICE: $52.24 Product Type: Paperback - Other Formats Published: April 2013 |
| Additional Information |
| BISAC Categories: - Technology & Engineering | Optics - Technology & Engineering | Electrical - Technology & Engineering | Lasers & Photonics |
| Dewey: 621.36 |
| Series: Lebedev Physics Institute |
| Physical Information: 0.42" H x 8.25" W x 11" (1.00 lbs) 188 pages |
| Descriptions, Reviews, Etc. |
| Publisher Description: The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 - SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi- lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec- tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre- 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re- 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated. |