| Hydroboration and Organic Synthesis: 9-Borabicyclo [3.3.1] Nonane (9-BBN) 2007 Edition Contributor(s): Dhillon, Ranjit S. (Author) |
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ISBN: 3540490752 ISBN-13: 9783540490753 Publisher: Springer OUR PRICE: $208.99 Product Type: Hardcover - Other Formats Published: May 2007 Annotation: 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN's derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations. |
| Additional Information |
| BISAC Categories: - Science | Chemistry - Organic - Science | Chemistry - Clinical - Science | Life Sciences - Biochemistry |
| Dewey: 547.23 |
| Physical Information: 1.47" H x 6.39" W x 9.31" (2.22 lbs) 604 pages |
| Descriptions, Reviews, Etc. |
| Publisher Description: 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN's derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations. |
