Hydroboration and Organic Synthesis: 9-Borabicyclo [3.3.1] Nonane (9-Bbn) Contributor(s): Dhillon, Ranjit S. (Author) |
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ISBN: 3642080340 ISBN-13: 9783642080340 Publisher: Springer OUR PRICE: $208.99 Product Type: Paperback - Other Formats Published: October 2010 |
Additional Information |
BISAC Categories: - Science | Chemistry - Organic - Science | Chemistry - Clinical - Science | Life Sciences - Biochemistry |
Dewey: 547 |
Physical Information: 1.22" H x 6.14" W x 9.21" (1.83 lbs) 586 pages |
Descriptions, Reviews, Etc. |
Publisher Description: 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN's derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations. |