| Novaya interpretatsiya v termodinamike Contributor(s): Maksimov Aleksandr (Author) |
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ISBN: 3659625469 ISBN-13: 9783659625466 Publisher: LAP Lambert Academic Publishing OUR PRICE: $40.94 Product Type: Paperback Language: Russian Published: October 2014 |
| Additional Information |
| BISAC Categories: - Science | Chemistry - Physical & Theoretical |
| Physical Information: 0.18" H x 6" W x 9" (0.27 lbs) 76 pages |
| Descriptions, Reviews, Etc. |
| Publisher Description: Novaya interpretatsiya v termodinamike pozvolyaet sistemno prosto i naglyadno ob"yasnit' izvestnye vazhneyshie zavisimosti i protsessy. Uravnenie sostoyaniya PV=RT imeet analiticheskuyu osnovu, a ne yavlyaetsya poluempiricheskim, kak eto bylo izvestno istoricheski. Na osnove izvestnoy obshchey zavisimosti teploemkosti v chastnykh proizvodnykh ot parametrov sostoyaniya polucheno differentsial'noe uravnenie zavisimosti ot temperatury s dvumya konstantami. Konstanty yavlyayutsya kharakteristikami konkretnogo veshchestva. Sopostavlenie so spravochnymi dannymi pokazalo khoroshee sootvetstvie. Uravnenie dopolnyaet fenomenologicheskoe opisanie termodinamiki. Na osnove velichin udel'noy teploemkosti rasschityvaetsya zavisimost' energii Gibbsa ot temperatury. Nachal'naya velichina pri nule temperatury opredelyaetsya pri nalichii koordinat eksperimental'noy tochki. Razrabotan metod rascheta geterogennogo ravnovesiya faz. Primer rascheta dlya vody-para pokazal khoroshee sootvetstvie s eksperimental'nymi dannymi, chto pozvolyaet ob"yasnit' otlichie real'nogo gaza ot ideal'nogo nalichiem ravnovesnogo kolichestva kondensata. |
